Others
日本語
Professor
Uno Hidemitsu

Research History

  1. 1984/06-1989/05Ehime UniversityAdvanced Instrumentation Center for Chemical AnalysisResearch Associate
  2. 1984-1989Advanced Instrumentation Center for Chemical Analysis, Ehime University
  3. 1989/06-2003/03Ehime UniversityAdvanced Instrumentation Center for Chemical AnalysisAssistant Professor
  4. 1989-2003Advanced Instrumentation Center for Chemical Analysis, Ehime University
  5. 2002/04-2002/09The Open University of JapanEhime Study CenterPart-time Senior Assistant Professorr
  6. 2002-2003The University of the Air
  7. 2003/04-2009/03Ehime UniversityIntegrated Center for SciencesProfessor
  8. 2003-2009Integrated Center for Sciences, Ehime University
  9. 2005/04-2006/03Kyushu UniversityInstitute for Materials Chemistry and EngineeringPart-time Senior Assistant Professorr
  10. 2006/04-2008/03Ehime UniversityTrustee
  11. 2008/04-2011/03The Open University of JapanEhime Study CenterVisiting Professor
  12. 2008/08-2011/03Kyushu UniversityInstitute for Materials Chemistry and EngineeringSpecially-appointed Professor
  13. 2008-2011University of Air
  14. 2008- Institute for Materials Chemistry and Engineering, Kyushu University
  15. 2009-presentEhime University大学院・理工学研究科Professor
  16. 2009- Department of Chemistry and Biology, Graduate School of Science and Engineering, Ehime University
  17. 2012/04-2013/03Ehime UniversityFaculty of ScienceVice Dean
  18. 2013/04-2015/03Ehime UniversityFaculty of ScienceDean
  19. 2015/04-presentEhime UniversityExecutive Director and Vice President

Education

  1. Kyoto University1976/041980/03
  2. Kyoto University1980/041982/03
  3. Kyoto University1982/041984/05
  4. Kyoto University1982

Degree

  1. Dr of ScienceKyoto University

Research Areas

Research Interests

  1. ペリ環状分解反応
  2. クムレン
  3. フロリン
  4. ポルフィリン
  5. 分子認識
  6. 近赤外色素
  7. ヘキサフィリン
  8. BODIPY
  9. テトラチオシン
  10. 消耗性電極
  11. 構造有機化学
  12. ピロロイソインドール
  13. 硫黄炭素混合電極
  14. グルタミン酸
  15. テトラベンゾポルフィリン
  16. 有機電子材料
  17. ペンタチエピン
  18. ボロンジピロメテン
  19. ビニルスルフィド
  20. トリフルオロメチル基
  21. ペンタセン
  22. ポルフィリノイド
  23. 逆Diels-Alder反応
  24. 高共役化合物
  25. キレトロピー分解反応
  26. ポルフィリシ
  27. 構造解析
  28. SS43405E
  29. 共役拡張ポルフィリノイド
  30. AH-1763 IIa
  31. コロネン
  32. ペリ環状反応
  33. 有機合成
  34. 有機化学
  35. 色素フィルター
  36. 抗ウイルス剤
  37. 抗生物質
  38. 有機発光ダイオード
  39. 有機トランジスタ
  40. 有機太陽電池
  41. Coronene
  42. Pentacene
  43. Porphyrinoid
  44. retro-Diels-Alder reaction
  45. pericyclic reaction
  46. Highly conjugated compounds
  47. Organic synthesis
  48. Organic chemistry
  49. Color filter
  50. Antivirus
  51. Antibiotics
  52. Organic light emitting diode
  53. Organic transistor
  54. Organic solar cell

Research Projects

  1. Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C)Construction of optically-active distorted pi-conjugated systems and their propertiesGrant-in-Aid for Scientific Research (C)2019/04/01-2023/03/01
  2. Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)Synthesis and fabrication of stimulus-convertible materials for single-molecular devicesGrant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)2013/06-2018/03Principal investigatorElectric measurement of single molecules which pi-systems were altered by external stimuli such as heat, light, acid, etc. was planned. Bicyclo[2.2.2]octadiene ring system was chosen as such an external-stimulus-changeable moiety and porphyrin, and hexapyrrolohexaazacoronene (HPHAC) were chosen as such pi-systems. In bisthiaporphyrins fused with BCOD and benzene rings, their macrocyclic ring current routes were altered from on a long axis to on short axes by protonation.
  3. Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)Molecular Architectonics: Orchestration of Single Molecules for Novel FunctionsGrant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)2013/06/28-2018/03/28We promoted joint studies by researchers in molecular design / synthesis, surface physics, molecular nanotechnology, semiconductor physics, information technology and theoretical physics, and published 591 papers on the following topics: (1) Precise design of molecules and molecular aggregates, (2) Structure and electronic state molecules on various electrodes, (3) Guiding principles for single molecular junctions showing nonlinear / asymmetrical current-voltage characteristics and switching characteristics by electric and magnetic field, and (4)Preparation of stochastic resonance devices utilizing the inherent noise of the element and the self-pulsating induced by voltage application. These results greatly contribute to progress in the field of single molecular electronics and open up research strategies on novel memory and computing systems based on molecular networks.
  4. Ehime UniversitySynthesis and fabrication of stimulus-convertible materials for single-molecular devicesGrant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)2013/06/28-2018/03/28
  5. Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)2,5-シクロヘキサジエン-1,4-ジラジカルの生成とその応用研究Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)2013/04/01-2014/03/01Principal investigator「2,5-シクロヘキサジエン-1,4-ジラジカルの生成とその応用研究」の採択を受けて、当初予定していた下記３課題の解決に取り組んだ。 課題① ピロロ[3,4-f]イソインドール前駆体の分解挙動とその生成物分析 課題② ピロロ[3,4-f]イソインドール–金属カルボニル錯体の合成 課題③ チオフェノ[3,4-f]イソインドール前駆体及びチオフェノ[3,4-f]イソチアナフテン前駆体の合成と反応およびその物性とそれらを用いた新奇π電子系化合物の合成 9-ヒドロキシ-4,8-メタノピロロ[3,4-f]イソインドールの酸化反応ではポリマーしか生成しない事がすでに判明していたので、この化合物のピロール窒素をメチル保護し、Parikh-Doeling酸化することでカルボニル架橋体を得て、熱挙動及び光分解挙動を検討するための合成を開始した。7-tert-ブトキシノルボルナジエンより誘導したジエチル＝9-ヒドロキシ-4,8-メタノピロロ[3,4-f]イソインドール-1,7-ジカーボキシレートを、NaHで処理ののちヨードメタンと反応させることによりN,N-ジメチル体を得た。これをParikh-Doeling酸化すると、徐々に分解反応が進行し混合物が得られた。この混合物の構造解析をしているところで、補助金事業の中止が決定した。当該申請のプロジェクトは、今後他の補助金事業により継続していくこととしている。
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Books and Other Publications

  1. 有機スペクトル解析 -MS・IR・NMRデータを読む臼杵 克之助 宇野 英満 築部 浩丸善出版2014/01/294621087606
  2. 有機スペクトル解析 : MS・IR・NMRデータを読む臼杵 克之助 宇野 英満 築部 浩丸善出版20149784621087602
  3. はじめての有機スペクトル解析 IR、NMR、MSデータを読む宇野 英満 築部 浩丸善株式会社2004/124621075055
  4. はじめての有機スペクトル解析 : IR、NMR、MSデータを読む宇野 英満 築部 浩丸善2004/129784621075050
  5. 第５版実験化学講座 １５ 「有機合成Ⅲ アルデヒド・ケトン・キノン」 日本化学会編 分担執筆丸善株式会社丸善2003
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Papers

  1. Radially π-Extended Pyrrole-Fused Azacoronene: A Series of Crystal Structures of HPHAC with Various Oxidation States.2021/02/01Sasaki Yoshiki,Takase Masayoshi,Kobayashi Nagao,Mori Shigeki,Ohara Keishi,Okujima Tetsuo,Uno HidemitsuThe Journal of organic chemistry10.1021/acs.joc.0c02825Radially π-extended hexapyrrolohexaazacoronene (HPHAC ) was synthesized in two steps with 2,5-di--butyl-acenaphtho[1,2-]pyrrole and hexafluorobenzene. Like its parent HPHAC , exhibited reversible oxidation behavior. Crystal structures of not only the neutral and dicationic compounds but also the radical cation were all revealed. While analyzing its peculiar structure, the formation of a 1:1 complex with C was observed in solution by NMR and absorption analyses. The spectroscopic analyses of and were performed based on magnetic circular dichroism and theoretical calculations.
  2. A cationic benzocorrole Cu(II) complex as a highly stable antiaromatic system.2021/01/14Wu Fan,Xu Jialiang,Gao Hu,Li Chenhong,Xu Shuai,Uno Hidemitsu,Xu Yan,Zhao Yue,Shen ZhenChemical communications (Cambridge, England)57/ 3, 383-38610.1039/d0cc06703bHere we report a highly stable 16π-electron antiaromatic system based on the ligand-oxidized Cu(ii)-tetrabenzocorrole. The antiaromaticity of the monocationic corrole complex was elucidated with the unique bond length alternation pattern of the crystal structure and the spectral diagnostic features. The NICS and GIMIC calculations clearly depicted its inner 15-membered-ring main pathway with a strong paratropic ring current.
  3. Manipulable Metal Catalyst for Nanographene Synthesis2020/11/11Akitoshi Shiotari Ikutaro Hamada Takahiro Nakae Shigeki Mori Tetsuo Okujima Hidemitsu Uno Hiroshi Sakaguchi Yuji Hamamoto Yoshitada Morikawa Yoshiaki SugimotoNano Letters20/ 11, 8339-8345Research paper (scientific journal)10.1021/acs.nanolett.0c03510URLAmerican Chemical Society (ACS)
  4. Synthesis and Properties of NitroHPHAC: The First Example of Substitution Reaction on HPHAC2020/05/27Yoshiki Sasaki Masayoshi Takase Shigeki Mori Hidemitsu UnoMolecules25/ 11, 2486-2486Research paper (scientific journal)10.3390/molecules25112486URLMDPI AGHexapyrrolohexaazacoronene (HPHAC) is one of the N-containing polycyclic aromatic hydrocarbons in which six pyrroles are fused circularly around a benzene. Despite the recent development of HPHAC analogues, there is no report on direct introduction of functional groups into the HPHAC skeleton. This work reports the first example of nitration reaction of decaethylHPHAC. The structures of nitrodecaethylHPHAC including neutral and two oxidized species (radical cation and dication), intramolecular charge transfer (ICT) character, and global aromaticity of the dication are discussed.
  5. Synthesis and Aromaticity of Benzene‐Fused Doubly N‐Confused Porphyrins2020/05/04Hidemitsu Uno Kota Muramatsu Shogo Hiraoka Hiroyuki Tahara Mako Hirose Eidai Tamura Tatsumi Shiraishi John Mack Nagao Kobayashi Shigeki Mori Tetsuo Okujima Masayoshi TakaseChemistry – A European Journal26/ 25, 5701-5708Research paper (scientific journal)10.1002/chem.202000339URLURL_2Wiley
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Presentations

  1. ヒドロキシフェニル基を有する1,5‐ジアザフルバレン骨格化合物の合成と物性複素環化学討論会講演要旨集2015/11/02URL
  2. ピロロ[3,4‐f]イソインドール骨格を有する二重N‐混乱ポルフィリノイドの合成と物性基礎有機化学討論会要旨集2015/09/24
  3. ポルフィリン‐ヘキサピロロヘキサアザコロネン二量体の合成と物性基礎有機化学討論会要旨集2015/09/24
  4. ベンゾポルフィリン希土類金属錯体の合成基礎有機化学討論会要旨集2015/09/24
  5. シクロ[8]ピロールホスホン酸塩の合成と物性基礎有機化学討論会要旨集2015/09/24
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Works

  1. 前駆体型有機エレクトロニクス材料の開発
  2. 超耐熱性可視光吸収色素及び色素増感用赤外吸収色素の開発2010-2011
  3. フタロシアニンブランチポリマーの開発2010-2011
  4. 有機ＥＬ発光材料の可溶化と塗布型プロセスへの適用2009-2010
  5. 臭素を含む機能材料の探索研究2009-2010
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Industrial Property Rights

  1. Patentボラジアジン系色素特願2013-1706762013/08/20特開2015-0402312015/03/02
  2. Patentビス−ボロンジピロメテン系色素特願2013-1706752013/08/20特開2015-0401762015/03/02
  3. Patent3−アミノフェノールの製造方法特願2013-0410262013/03/01特開2014-1337302014/07/24
  4. Patentビス−ボロンジピロメテン系色素及びその前駆体特願2012-2802502012/12/21特開2013-1775512013/09/09
  5. Patentイソインドール類およびそのポリマー特願2013-0789922013/04/04特開2013-1296822013/07/04
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Awards

  1. 1989/11有機合成協会中国四国支部奨励賞
  2. 1989Aword of Synthetic Organic Chemistry Chugoku-Shikoku Division
  3. 1984/07野津奨励賞
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Allotted Class

  1. 2024Scientific Research
  2. 2024Seminar in Chemistry Ⅰ
  3. 2024Seminar in Chemistry Ⅲ
  4. 2024Practical Seminar in Molecular Science Ⅰ
  5. 2024Advanced Lecture on Biological Materials Ⅱ
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Professional Memberships

  1. Chemical Society of Japan
  2. Synthetic Organic Chemistry
  3. Electrochemical Society of Japan
  4. International Society of Heterocyclic Chemistry
  5. Society of Porphyrins and Phthalocyanines
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Committee Memberships

  1. 2014/04-present基礎有機化学会理事
  2. 2009/03-2011/02有機合成協会評議員
  3. 2009-2011Synthetic Organic Chemistry評議員
  4. 2008/03-present臭素化学懇話会会長
  5. 2007/03-present有機合成協会中国四国支部幹事
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